EtOH reduces the solubility of DNA


EtOH reduces the solubility of DNA

  • DNA normally stays dissolved in water because DNA is surrounded by a shell of water molecules, because water sticks to its charged phosphate backbone
  • When ethanol is added, it competes with water and reduces the number of water molecules that can surround DNA
  • So the “protective water coat” around DNA becomes weak or incomplete
  • Without that coat, DNA strands are no longer well-separated and stabilized in solution
Salt increases the precipitation of DNA
  • A salt (like NaCl or sodium acetate) is usually already added in the extraction mix, and it helps reduce repulsion between DNA strands, making clumping easier
  • Once clumped, DNA becomes visible as a white precipitate, which can be collected easily 

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